INVESTIGATION OF DIMETHYL DIALLYLAMMONIUM CHLORIDE AND DIMETHYL ACRYLAMIDE SYNTHESIS AND KINETICS
Abstract
Radical co-polymerization of N, N-dimethyl-N,N-diallyammonium chloride (DMDAAC) with N,N-dimethyl acrylamide (DMAA) has been investigated by the dilatometer technique using ammonium persulfate ((NH4)2S2O8) as an initiator. The influences of the molar ratio of DMDAAC to DMAA, concentrations of monomers and initiator, temperature on polymerization rate have been analysed. From these analysis it was found that DMDAAC concentration in monomers composition conversely affects the polymerization rate. Based on the experimental results, the polymerization mechanisms were discussed in more detail.
About the Authors
Е. SyrgabekKazakhstan
A. Akhmetzhan
Kazakhstan
Zh. Toktarbay
Kazakhstan
Almaty
A. Tashenov
Kazakhstan
N. Nuraje
United States
Lubbock
References
1. Moad G, Solomon DH. Inroduction. In: Moad G, Solomon DH. The Chemistry of Radical Polymerization; 2nd ed. Oxford: Elsevier; 2006. p. 1-9.
2. Nesvadba P. Radical Polymerization in Industry. In: Chatgilialoglu C, Studer A, editors. Encyclopedia of Radicals in Chemistry, Biology and Materials. Vol 4. Chichester: John Wiley & Sons, Ltd; 2012. p. 1701-1736.
3. K.Zh. Abdiyev, Z. Toktarbay, A.Zh. Zhenissova, M.B. Zhursumbaeva, R.N. Kainazarova, N. Nuraje, The New effective FlocculantsndashCopolymers of N,N-dimethyl-N,N-diallylammonium Chloride and N,N-dimethylacrylamide, Colloids and Surfaces A: Physicochemical and Engineering Aspects (2015)
4. N. Maximova, M. Цsterberg, K. Koljonen and P. Stenius, Lignin adsorption on cellulose fibre surfaces: effect on surface chemistry, surface morphology and paper strength, Cellulose. 8 (2001) 113-125.5.
5. Matthew P. Mullarney, Thomas A.P. Seery, R.A. Weiss Drug diffusion in hydrophobically modified N,N-dimethylacrylamide hydrogels// Polymer 47 (2006) 3845–3855
6. Vijay Shankar Pandey, Shiv Kumar Verma, Mithilesh Yadav, Kunj Behari Studies on graft copolymerization of gellan gum with N,N-dimethylacrylamide by the redox system// International Journal of Biological Macromolecules 70 (2014) 108–115
7. A.L. Ramos-Jacques, J.A. Lujan-Montelongo, Silva-Cuevas, M. Cortez-Valadez, M. Estevez, A.R. Hernandez-Martínez Lead (II) removal by poly(N,N-dimethylacrylamide-co-2-hydroxyethyl methacrylate)// European Polymer Journal 101 (2018) 262–272
8. Hideaki Tokuyama, Eri Kitamura, Yoshimi Seida Detection of AU(III) ions using a poly(N,Ndimethylacrylamide)- coated QCM sensor// Talanta 146 (2016) 507–509
9. Nowers, J.R., Narasimhan, B., “The effect of interpenetrating polymer network formation on polymerization kinetics in an epoxy[hyphen (true graphic)]acrylate system”, Polymer, 47 (4), 1108-1118 (2006).
10. Choi, E.C., Jin, S.M., Park, Y.J., Kim, Y., “Polymerization kinetics for the preparation of poly(pdivinylbenzene) via a miniemulsion polymerization process”, J. Chin. Inst. Chem. Eng., 39 (5), 483-488 (2008).
11. Cutie SS, Smith PB, Henton DE, Staples TL, Powell C (1997) Acrylic acid polymerization kinetics. J Polym Sci Part B Polym Phys 35:2029–204712.
12. K. Zh. Abdiyev, Zh. Toktarbay, A. Zh. Zhenissova, M. B. Zhursumbaeva, and R. N. Kainazarova Copolymerization of N,N-dimethyll-N,N-diallylammonium Chloride with N,Ndimethylacrylamide// Polymer Science, Ser. B, 2015, Vol. 57, No. 3, pp. 217–223.
13. Rintoul I, Wandrey C (2005) Approach to predict copolymer compositions in case of variable monomer reactivity. Macromolecules 38:8108–8115
14. Mahdi Abdollahi, Parisa Alamdari, Hadis Koolivand, Farshid Ziaee A comprehensive study on the kinetics of aqueous free-radical homo- and co-polymerization of acrylamide and diallyldimethylammonium chloride by online 1H-NMR spectroscopy// J Polym Res (2013) 20:239.
15. E. Nadim, H. Bouhendi, F. Ziaee, R. Bazhrang Kinetic study of 2-acrylamido-2-methylpropanesulfonic acid in free-radical polymerization method by differential scanning calorimetry// Polym. Bull. (2012) 68:405–414.
16. Pham Q-Thai, Hsu Y-Jung, Wang F-Ming, Chern C-Shyan, Mechanisms and kinetics of nonisothermal polymerization of N,N-bismaleimide-4,4-diphenylmethane with 2-thiobarbituric acid, Thermochimica Acta (2018), https://doi.org/10.1016/j.tca.2018.08.01617.
17. E. E. Ergozhin, B. A. Mukhitdinova, S. A. Shoinbekova, A. I. Nikitina, and B. M. Nuranbaeva Kinetics of Radical Polymerization of a Monomer Derived from Monoethanolamine Vinyl Ether and 1,4-Benzoquinone: A Polarographic Study// Russian Journal of Applied Chemistry, Vol. 76, No. 3, 2003, pp. 460 – 463.
18. Marco Fantin, Abdirisak A. Isse, Nicola Bortolamei, Krzysztof Matyjaszewski, Armando Gennaro Electrochemical approaches to the determination of rate constants for the activation step in atom transfer radical polymerization// Electrochimica Acta 222 (2016) 393–401.
19. Hong-Ru Lin Solution polymerization of acrylamide using potassium persulfate as an initiator: kinetic studies, temperature and pH dependence// European Polymer Journal 37 (2001) 1507-1510.
20. LIAO Liewen, YUE Hangbo, and CUI Yingde Crosslink Polymerization Kinetics and Mechanism of Hydrogels Composed of Acrylic Acid and 2-Acrylamido-2-methylpropane Sulfonic Acid// Chinese Journal of Chemical Engineering, 19(2) 285-291 (2011)
21. De, Gee A., Davidson, C., Smith, A., “A modified dilatometer for continuous recording of volumetric polymerization shrinkage of composite restorative materials”, J. Dent., 9 (1), 36-42 (1981).
22. Watts, D., Cash, A., “Determination of polymerization shrinkage kinetics in visible-light-cured materials: Methods development”, Dent. Mater., 7 (4), 281-287 (1991).
23. Venhoven, B., De, Gee A., Davidson, C., “Polymerization contraction and conversion of lightcuring BisGMA-based methacrylate resins”, Biomaterials, 14 (11), 871-875 (1993).
24. Braga, R.R., Ferracane, J.L., “Contraction stress related to degree of conversion and reaction kinetics”, J. Dent. Res., 81 (2), 114-118 (2002). 25. Yebol Dauletov, Kaldybek Abdiyev, Zhexenbek Toktarbay, Nurxat Nuraje, Maryamgul Zhursumbaeva, and Bagdaulet Kenzhaliyev Radical Polymerization and Kinetics of N,N-diallyl-N,N-dimethylammonium Chloride and Vinyl Ether of Monoethanolamine// Fibers and Polymers 2018, Vol.19, No.10, 2023-202926. Kezhen Bi, Yuejun Zhang Kinetic Study of the Polymerization of Dimethyldiallylammonium Chloride and Acrylamide// J Appl Polym Sci – 2012, Vol.125, -1636–1641.
Review
For citations:
Syrgabek Е., Akhmetzhan A., Toktarbay Zh., Tashenov A., Nuraje N. INVESTIGATION OF DIMETHYL DIALLYLAMMONIUM CHLORIDE AND DIMETHYL ACRYLAMIDE SYNTHESIS AND KINETICS. Herald of the Kazakh-British technical university. 2020;17(2):141-146.