kaz29Вестник Казахстанско-Британского технического университетаHerald of the Kazakh-British Technical University1998-66882959-8109Казахстанско-Британский Технический Университетkaz29-160Research ArticleХИМИКО-ТЕХНОЛОГИЧЕСКИЕ НАУКИ И ЭКОЛОГИЯCHEMICAL, TECHNOLOGICAL AND ENVIRONMENTAL SCIENCESИССЛЕДОВАНИЕ СИНТЕЗА И КИНЕТИКИ ДИМЕТИЛДИАЛЛИЛАММОНИЙ ХЛОРИДА И ДИМЕТИЛ АКРИЛАМИДАINVESTIGATION OF DIMETHYL DIALLYLAMMONIUM CHLORIDE AND DIMETHYL ACRYLAMIDE SYNTHESIS AND KINETICSСыргабекЕ.SyrgabekЕ.

магистрант

АхметжановаГ. А.AkhmetzhanA.

докторант

ТоқтарбайЖ.ToktarbayZh.

PhD

Almaty

ТашеновА.TashenovA.

профессор

НұражеН.NurajeN.

Лаббок

Lubbock

Казахский Национальный университет им. аль-ФарабиКазахстанAl-Farabi Kazakh National UniversityKazakhstanСәтбаев университетіКазахстанL.N.Gumilyov Eurasian National UniversityKazakhstanКазахский Национальный университет им. аль-ФарабиКазахстанAl-Farabi Kazakh National University; Specialized gymnasium for gifted children teaching in three languages named after Al-FarabiKazakhstanЕвразийский Национальный университет им. Л.Н. ГумилеваКазахстанL.N.Gumilyov Eurasian National UniversityKazakhstanТехасский технический университетСоединённые Штаты АмерикиTech UniversityUnited States202007112021172141146Copyright © Сыргабек Е., Ахметжанова Г.А., Тоқтарбай Ж., Ташенов А., Нұраже Н., 20212021Сыргабек Е., Ахметжанова Г.А., Тоқтарбай Ж., Ташенов А., Нұраже Н.Syrgabek Е., Akhmetzhan A., Toktarbay Z., Tashenov A., Nuraje N.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestnik.kbtu.edu.kz/jour/article/view/160

Радикальная сополимеризация N, N-диметил-N, N-диаллиаммоний хлорида (ДМДААХ) с N, N-диметилакриламидом (ДМАА) была исследована методом дилатометра с использованием персульфата аммония ((NH4)2S2O8) в качестве инициатора. Проанализировано влияние молярного отношения ДМДААХ к ДМАА, концентрации мономеров и инициатора, температуры на скорость полимеризации. Из этого анализа было установлено, что концентрация ДМДААХ в составе мономеров, наоборот, влияет на скорость полимеризации. Основываясь на экспериментальных результатах, механизмы полимеризации обсуждались более подробно.

Radical co-polymerization of N, N-dimethyl-N,N-diallyammonium chloride (DMDAAC) with N,N-dimethyl acrylamide (DMAA) has been investigated by the dilatometer technique using ammonium persulfate ((NH4)2S2O8) as an initiator. The influences of the molar ratio of DMDAAC to DMAA, concentrations of monomers and initiator, temperature on polymerization rate have been analysed. From these analysis it was found that DMDAAC concentration in monomers composition conversely affects the polymerization rate. Based on the experimental results, the polymerization mechanisms were discussed in more detail.

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The authors declare that there are no conflicts of interest present.