CATALYSTS OF THE HYDROCARBONS CONVERSION FOR LONG-CHAIN α-OLEFINS OBTAINMENT
Abstract
A literature review on the catalysts, used in the hydrocarbons conversion to produce a-olefins, is given in the article. The catalysts derived from natural raw materials are considered as the most accessible ones. Methods of decationization and modification of dinoptiUolite, the main component of natural zeolites of Russia and Kazakhstan, are described. Montmorillonite clay is used as a carrier. The most attention in the cracking catalysts review was drawn in the direction of the paraffin cracking with obtainment of long-chain a-olefins. The production of long-chain a-olefins by the oligomerization of ethylene and propylene, where Bronsted and Lewis acids are used as catalysts, is shown along with cracking. In addition to natural and synthetic zeolites, heteropoly acid (HPA) is also used in the catalysts production.
About the Authors
L. Krebayeva
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
Zh. Algabas
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
References
1. Dolgov B. N. Catalysis in organical chemistry. GKhl. L. - 1959. - 807 p.
2. High olefins. Production and application. Ed. by Dalin M. A. - L.. Khimiya. 1984. - 264 p.
3. Geyts B., Kettsir Dzh., Shuyt G. Chemistry of catalytic processes. - M.: Mir. 1981. - 551 p.
4. Akhmetov S. A. Technology of deep treatment of oil and gas. - Ufa. Gilem. 2002. - 672 p.
5. Sokolskiy D. V. Hydratation in solutions. - Alma-Ata: Nauka KazSSR. - 1979. - 364 p.
6. Konuspayev S. R., Kadirbekov K. A., Sarsekova A. T., Nurbayeva R. K., Zhambakin D. G. Cata lytic synthesis of high a-olefins by paraffine cracking. // Neftekhimiya. - 2010. - Tom 50. No 5. - P. 378-382.
7. Krylov O. V. Theory of heterogeneous catalysis. - M.: “Akademkniga”. 2004. - 679 p.
8. Zakumbayeva G. D., Shapovalova L. B., Dostiyarov A. M. Treatment of synthesis gas and waste gases of industry. Chemistry and sustainable development «CHEMRAN-Vin». - M. - 1992. - P.30.
9. Li Shuai, Zhang Jie, Nie Guanghua. Determination of the ratio of silicon / aluminum in the zeo lite molecular sieve connecting iron. // Wyiyan gongue= inorg. Chem. Ind. - 2012. - Т.44, No 1. - P. 59-60.
10. Battalova Sh.B. Physicochemical bases of obtainment and application of catalysts ans adsorbents and bentonites. - Alma-ata: Nauka. 1986. -168p.
11. Evdokimova V. A., Karatsuba L. P., Lankin S. V. Variation of adsorption properties of clinoptilolite as a result of cation-exchange // Perspekt. Mater. - 2011. No 13. - P. 497-501.
12. Makarov A. E., Melnikov V. B., Glagoleva O. F. Influence of the filler on the properties of zeo lite-containing cracking catalysts. // Chemistry and Technol. fuels and oils. 2006. No 3. - P. 39-40.
Review
For citations:
Krebayeva L., Algabas Zh. CATALYSTS OF THE HYDROCARBONS CONVERSION FOR LONG-CHAIN α-OLEFINS OBTAINMENT. Herald of the Kazakh-British technical university. 2019;16(3):460-464.
Views:
270
Email this article 