A REVIEW ON ANTI-ADSORPTION BEHAVIORS OF PARTIALLY HYDROLYZED POLYACRYLAMIDE IN RESERVOIR FORMATIONS
https://doi.org/10.55452/1998-6688-2025-22-4-432-443
Abstract
Polymer flooding is one of the key technologies for enhancing oil recovery. Partially Hydrolyzed Polyacrylamide (HPAM) is widely used due to its excellent viscosity-increasing properties. However, the adsorption and retention behavior of HPAM in reservoir porous media presents a dual effect: on one hand, it improves sweep efficiency by increasing flow resistance; on the other hand, it leads to a loss in effective polymer concentration and viscosity, reducing displacement efficiency and increasing costs. Therefore, a systematic understanding and control of HPAM adsorption behavior are crucial for improving the effectiveness of polymer flooding. This work systematically reviews seven main measurement methods for HPAM adsorption quantity, comparing their applicable conditions and limitations. It summarizes the key factors influencing HPAM adsorption and retention behavior from three aspects: polymer properties, rock mineral characteristics, and reservoir environmental conditions. Furthermore, it outlines chemical anti-adsorption methods, represented by competitive adsorption and nanofilm protection, along with their mechanisms. Finally, future research directions are proposed, focusing on building adsorption prediction models, deepening the understanding of adsorption mechanisms under multi-field coupling conditions, and developing novel functional polymers with anti-adsorption capabilities.
About the Authors
Haobin ShiChina
Master’s student
Qingdao
Hongbin Yang
China
Associate Professor
Qingdao
Xin Chen
China
Master’s student
Qingdao
Liang Peng
China
Master’s student
Qingdao
Shuhe Zhang
China
Master’s student
Qingdao
Wanli Kang
China
Professor
Karamay
Abdusamig Kadirov
Uzbekistan
Professor
Tashkent
References
1. Yang, J., Li, H., Huang, P. The Static adsorption of HPAM on porous media –influence of hydrolysis degree on the quantity of adsorbed HPAM. Journal of Polymer Science, 05, 90–94 (1997).
2. Lai, N., Zhang, Y., Zhao, X., et al. Adsorption and retention characteristic of hyperbranched polymers in porous media. Chemical Research and Application, 028(003), 360–365 (2016).
3. Li, Y., Qu, Y. Influence of kaoline to static adsorption and dynamical retention of polyacrylamide [J]. Offshore oil, 30(02), 72–76 (2010).
4. Liu, X., Chen, Z., Zeng, F. Effect of mineral property on the adsorption of polyacrylamide [J]. Mineralogy and Petrology, 01, 97–100 (2004).
5. Li, Y., Qu, C. Research on dynamic hold-up of water-soluble polymer in porous medium [J]. Oil Drilling & Production Technology, 33(01),76–79 (2011).
6. Sun, X., Zhang, W., Li, J., et al. Mechanism and Performance Analysis of Nanoparticle-Polymer Fluid for Enhanced Oil Recovery: A Review. [J]. Molecules (Basel, Switzerland), 2023, 28(11).
7. Pi, Y., Liu, J., Cao, R., et al. Visualized Study on a New Preformed Particle Gels (PPG) + Polymer System to Enhance Oil Recovery by Oil Saturation Monitoring Online Flooding Experiment [J]. Gels, 9(2), 81 (2023).
8. Guan, S., Fan, H., Wu, S., et al. Determination of Polyacrylamide Mass Concentration – Turbidity Method [J]. Journal of Northeast Petroleum University, 31(2), 106–109 (2007).
9. Zhou, X., Tang, S., Sheng, H., et al. Overview of Polyacrylamide Concentration Measurement Methods [J]. Guangzhou Chemical Industry, 47(16), 4 (2019).
10. Zhu, H., Cai, Y., Wei, Y, et al. Concentration measurement of novel water-soluble polymers used in EOR with ultraviolet spectroscopy [J]. Fine and Specialty Chemicals, 12(6), 4 (2004).
11. Li, J., Yan, X. A new method for determining concentration loss of oil displacement polymer by static adsorption and its application [J]. Petrochemical Technology, 53(6), 884–889 (2024).
12. Li, Q. Research progress on polyacrylamide concentration detection methods [J]. Chemical Management, 17, 1 (2016).
13. Kong, B. Overview of Polyacrylamide Concentration Measurement Methods [J]. Oilfield Chemistry, 13(3), 6 (1996).
14. Xu, T., Cao, T., Huang, J., et al. Blockage of Polymers in High Permeability Cores and Mechanism of Reactive Anti-adsorption System [J]. Contemporary Chemical Industry, 2021.
15. Yang, L., Liu, Y., Wu, X., et al. The research status and summary of adsorption and retention mechanism of polymer[J]. IOP Conference Series: Materials Science and Engineering, 892(1), 012023 (2020).
16. Hu, J., Li, X., Han, C. An Experimental Study on The Dynamic Adsorption of Partially Hydrolyzed Polyacrylamides in Porous Media [J]. Oilfield Chemistry, (4), 5 (1991).
17. Li, J., Lan, L., Xiao, M., et al. Research on the Adsorption Behavior of Polyacrylamide on the Surfaces of Shale and Sandstone [J]. Standard Science, (S1)(2025).
18. Fu, M., Zhang, Z., Hou, B., et al. Polymer plugging mechanism and prevent technology of polymer injection wells in Henan Oilfield [J]. Journal of Yangtze University (Natural Science Edition) ,18(03), 37–48 (2021).
19. Gao, S., Chen, Y., Wang, X., et al. Research on Dynamic Performance of Anti-polymer Adsorbent in Henan Oilfield [J]. Contemporary Chemical Industry, 50(09), 2170–2175 (2021).
20. Guo, Y., Li, F., Li, L., et al. Adsorption Behavior of Water-Soluble Hydrophobic Associative Polymer at Water/Kaolin Interface [J]. Chinese Journal of Applied Chemistry, (01), 26–29 (2002).
21. Zhou, Y. The Interaction between Polymer and Surfactant Binary System [D]. Southwest Petroleum Institute, 2005.
22. Xue, G., Zhu, H. Nanofilm anti adsorption technology [J]. Chemical Engineering & Equipment, (02), 84–85 (2021).
Review
For citations:
Shi H., Yang H., Chen X., Peng L., Zhang Sh., Kang W., Kadirov A. A REVIEW ON ANTI-ADSORPTION BEHAVIORS OF PARTIALLY HYDROLYZED POLYACRYLAMIDE IN RESERVOIR FORMATIONS. Herald of the Kazakh-British Technical University. 2025;22(4):432-443. https://doi.org/10.55452/1998-6688-2025-22-4-432-443
JATS XML





