Preview

Herald of the Kazakh-British technical university

Advanced search

OPTIMIZATION OF THE PLASMA-CHEMICAL SYNTHESIS PROCESS OF FULLERENES

Abstract

Studying the features of the synthesis of fullerenes will make it possible to understand the process of formation of nanostructures of this class. Increasing the yield of fullerenes and purity will allow us to approach the creation of new materials of an economic class. This work is devoted to the experimental method for producing fullerenes by the arc discharge method. It was found that the purity and yield of fullerenes depend on the synthesis parameters, in particular the gas pressure, on the voltage, on the current strength, and also on the preparation of the electrodes. This paper shows the desorption of graphite electrodes without the use of auxiliary equipment. For the synthesis of fullerenes, a reactor assembled according to the Kretchmer principle was used, extraction was carried out with toluene solution. (Must be supplemented with at least 150 words should be)

About the Authors

N. Akhanova
Казахстанско-Британский технический университет
Kazakhstan


M. Gabdullin
Казахстанско-Британский технический университет
Kazakhstan


D. Schur
Институт проблем Материаловедения им. И.Н. Францевича
Ukraine


References

1. Edison Castro, Andrea Hernandez Garcia, Gerardo Zavala, and Luis Echegoye, Fullerenes in biology and medicine. Journal of Materials Chemistry B, 2017, 32, 1-14.

2. H. Kataoka, T. Ohe, K. Takahashi, S. Nakamura and T. Mashino. Bioor. Med. Chem. Lett. 2016, 26, 4565-4567.

3. E. Castro, Z. S. Martinez, C. S. Seong, A. Cabrera-Espinoza, M. Ruiz, G. Hernandez, A, F. Valdez, M. Llano and L. A. Echegoyen. J. Med. Chem. 2016, 59, 10963-10973

4. Y. Zhang, T. Dai, M. Wang, D. Vecchio, L. Y. Chiang and M. R. Hamblin. Nanomedicine. 2015, 10, 603-614

5. M. Guan, J. Ge, J. Wu, G. Zhang, D. Chen, W. Zhang, Y. Zhang, T. Zou, M. Zhen, C. Wang, T. Chu, X. Hao and C. Shu. Biomaterials. 2016, 103, 75-85.

6. N. Shershakova, E. Baraboshkina, S. Andreev, D. Purgina, I. Struchkova, O. Kamyshnikov, A. Nikonova and M. Khaitov. J. Nanobiotechnol. 2016, 14, 8

7. J. Tang, Z. Chen, B. Sun, J. Dong, J. Liu, H. Zhou, L. Wang, R. Bai, Q. Miao, Y. Zhao, C. Chen and Y. Liu. Nanomedicine: NBM. 2016, 12, 945-954.

8. Zhang, X. R.; Cao, D. P.; Chen, J. F., Hydrogen adsorption storage on single-walled carbon nanotube arrays by a combination of classical potential and density functional theory. Journal of Physical Chemistry B 2003, 107, (21), 4942-4950.

9. A. M. El Mahdy, DFT study of hydrogen storage in Pd-decorated C60 fullerene, Molecular Physics. An International Journal at the Interface Between Chemistry and Physics, 113:22, 3531-3544, 2015

10. Jin C., Hettich R., Compton R., Joyce D., Blencoe J., Burch T. Direct solid-phase hydrogenation of fullerenes// J. Phes. Chem. – 1994. – V.98. – P.4215.

11. Otarbay, Zh.E.,Gabdullin, M.T.,Abdullin, Kh.A.,Shur, D.V.,Ismailov, D.V., Yerlanuly, Y.,Kerimbekov, D.S., Hydrogenization of fullerene as a method of storage of hydrogen//Journal of Physics: Conference Series – 2018 – V.987, №1. – P.012025

12. Dan Liu, Wenjie Zhao, Shuan Liu, Qihong Cen, QunjiXue, Comparative tribological and corrosion resistance properties of epoxy composite coatings reinforced with functionalized fullerene C60 and grapheme// Surface & Coatings Technology – 2016 – Vol. 286 – P.354-364

13. Bogumił Eugeniusz Brycki, Iwona H. Kowalczyk, Adrianna Szulc, Olga Kaczerewska and Marta Pakiet, Organic Corrosion Inhibitors, December 20th 2017.

14. T.J.Behbahani , A. A. M.Beigi, Z. Taheri, B. Ghanbari, The effect of amino [60] fullerene derivatives on pour point and rheological properties of waxy crude oil// Journal of Molecular Liquids - 2015 – Vol. 58, – P. 308–314

15. Kratschmer W., Lamb L.D., Fostiropoulos K., Huffman D.R. Nature, V.347, № 354 (1990)

16. Х.А. Абдуллин, М.Т. Габдуллин, Т.С. Рамазанов, Д.Г. Батрышев, Д.В. Исмаилов, Д.В. Щур. Синтез фуллеренов в дуговом разряде // ВестникКазНУ, серия физическая, 2015. – Т. 52. – №1. – С. 40-45.

17. Anabel Ruiz-Espinoza, Estrella Ramos, Roberto Salcedo, Theoretical description of benzene–fullerene and its organometallic derivative // Computational and Theoretical Chemistry, Volume 1016,15 July 2013, Pages 36-41

18. N. Jargalan, T. V. Tropin, M. V. Avdeev,V. L. Aksenov, Investigation of the dissolution kinetics of fullerene C60 in solvents with different polarities by UV-Vis spectroscopy, Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques, volume 9,pages12–16, 2015.

19. Saba Goodarzi, Тatiana Da Ros,JoãoConde,FarshidSefat,MasoudMozafari, Fulleren: biomedical engineers get to revisit an old friend, Materials Today Volume 20,Number 8 October 2017, 460-480.

20. Kasturi Vimalanathan, Rekha GoswamiS hrestha, Zhi Zhang, Jin Zou, Tomonobu Nakayama, and Colin L. Raston, Surfactant-free Fabrication of Fullerene C60 Nanotubules Under Shear, Published in AngewandteChemie 2017, 1-5.

21. Jahangir Ahmad Rather, AbirJumaa Al Harthi,Emad A. Khudaish,AhsanulhaqQurashi,Abdul Munam, Palanisamy Kannan, An electrochemical sensor based on fullerene nanorods for the detection of paraben, an endocrine disruptor, Analitical Methods,28, 2016.

22. Jungah Kim, Chibeom Park, Intek Song, Minkyung Lee, Hyungki Kim, HeeCheul Choi, Unique Crystallization of Fullerenes: Fullerene Flowers, Scientific Reports, volume 6, Article number: 32205, 2016.


Review

For citations:


Akhanova N., Gabdullin M., Schur D. OPTIMIZATION OF THE PLASMA-CHEMICAL SYNTHESIS PROCESS OF FULLERENES. Herald of the Kazakh-British technical university. 2020;17(3):119-124. (In Russ.)

Views: 316


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 1998-6688 (Print)
ISSN 2959-8109 (Online)