HYDROGENATION OF POLY-a-OLEFINS ON SUPPORTED PALLADIUM CATALYSTS
Abstract
In the present work, before metal loading, the raw diatomite was modified by thermal treatment and acid activation with hydrochloric solution, to obtain the catalyst support suitable for use in hydrogenation of vegetable oils. Changes in surface structure and morphology of diatomite samples has been characterized by scanning electron microscopy, X-ray fluorescence, and nitrogen adsorption (BET). 1.0% Pd/D-HCI-500 catalysts with 1.0wt.% Pd content supported on activated diatomite were prepared by an adsorption method, average size of palladium particles were determined by high resolution transmission electron microscopy. The activities o f the catalyst was tested for poly-a-olefins hydrogenation reaction in a batch reactor (Parr-4848) operated under 1.0 MPa pressure and at reaction temperature 900C.
About the Authors
K. Toshtay
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
S. K. Toktasynov
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
E. A. Aubakirov
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
R. S. Bashirbaeva
Казахский Национальный университет им. аль-Фараби
Kazakhstan
Kazakhstan
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Review
For citations:
Toshtay K., Toktasynov S.K., Aubakirov E.A., Bashirbaeva R.S. HYDROGENATION OF POLY-a-OLEFINS ON SUPPORTED PALLADIUM CATALYSTS. Herald of the Kazakh-British technical university. 2019;16(2):60-66. (In Russ.)
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