kaz29Вестник Казахстанско-Британского технического университетаHerald of the Kazakh-British Technical University1998-66882959-8109Казахстанско-Британский Технический Университетkaz29-185Research ArticleХИМИКО-ТЕХНОЛОГИЧЕСКИЕ НАУКИ И ЭКОЛОГИЯCHEMICAL, TECHNOLOGICAL AND ENVIRONMENTAL SCIENCESОБЗОР СО-СОДЕРЖАЩИХ ПЕРОВСКИТОПОДОБНЫХ КАТАЛИЗАТОРОВ. СИНТЕЗ И ПРИМЕНЕНИЕREVIEW OF CО-CONTAINING PEROVSKY-LIKE CATALYSTS. SYNTHESIS AND APPLICATIONДжетписбаеваГ. Д.JetpisbayevaG.

докторант

МасалимоваБ. К.MassalimovaB.

к.х.н., доцент

Таразский государственный университет им. М.Х. Дулати2020081120211735462Copyright © Джетписбаева Г.Д., Масалимова Б.К., 20212021Джетписбаева Г.Д., Масалимова Б.К.Jetpisbayeva G., Massalimova B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestnik.kbtu.edu.kz/jour/article/view/185

В настоящее время сложные оксиды со структурой перовскита широко используются в катализе благодаря уникальному набору физико-химических свойств. В связи с этим в работе рассмотрены важнейшие научные труды по методам синтеза и изучения физико-химических свойств Со-содержащих катализаторов со структурой перовскита, используемых в синтезе Фишера-Тропша. К перовскитоподобным оксидам относится многочисленный ряд смешанных оксидов общей формулы ABO3, где в качестве катионов А и В могут выступать катионы металлов, которые удовлетворяют условию электронейтральности (суммарный заряд +6) и определенным стерическим соотношениям. Катионы А обычно имеют ионные радиусы, близкие к кислородному, и могут быть представлены редкоземельными (La, Pr, Sm, Ce), щелочноземельными (Ca, Mg, Ba, Sr) либо щелочными (Na, K) металлами. Катионы в положении В должны иметь значительно меньший ионный радиус, и в этом качестве могут выступать большинство переходных металлов (Fe, Ni, Co, Cu, Ti, Cr, Ru, Mn и др.). Золь-гель, цитратный и механохимические методы широко используются при синтезе катализаторов со структурой перовскита. Активность и селективность катализаторов со структурой перовскита зависят от способа синтеза, размера площади поверхности, а также от природы носителя.

Currently, complex oxides with a perovskite structure are widely used in catalysis due to a unique set of physicochemical properties. In this regard, the most important scientific works on the methods of synthesis and study of the physicochemical properties of containing catalysts with a perovskite structure used in the Fischer-Tropsch synthesis are considered. Perovskite-like oxides include a large number of mixed oxides of the general formula ABO3, where metal cations that satisfy the electroneutrality condition (total charge +6) and certain steric ratios can act as cations A and B. Cations A usually have ionic radii close to oxygen and can be represented by rare earth (La, Pr, Sm, Ce), alkaline earth (Ca, Mg, Ba, Sr) or alkaline (Na, K) metals. The cations in position B should have a significantly smaller ionic radius, and most transition metals (Fe, Ni, Co, Cu, Ti, Cr, Ru, Mn, etc.) can play this role. Sol gel, citrate, and mechanochemical methods are widely used in the synthesis of perovskite catalysts. The activity and selectivity of perovskite catalysts depend on the synthesis method, the size of the surface area, and also on the nature of the support.

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The authors declare that there are no conflicts of interest present.