kaz29Вестник Казахстанско-Британского технического университетаHerald of the Kazakh-British Technical University1998-66882959-8109Казахстанско-Британский Технический Университет10.55452/1998-6688-2024-21-4-210-218kaz29-1552Research ArticleФИЗИЧЕСКИЕ НАУКИPHYSICAL SCIENCESПЛАЗМОННЫЙ РЕЗОНАНС В ТОНКИХ ПЛЕНКАХ ZnO С НАНОЧАСТИЦАМИ БЛАГОРОДНЫХ МЕТАЛЛОВPLASMON RESONANCE IN THIN ZnO FILMS WITH NANOPARTICLES OF NOBLE METALShttps://orcid.org/0009-0003-6842-2955КошановаА. Б.KoshanovaA. B.

докторант

г. Алматы

doctoral student

Almaty

aizhankoshanova.kz@gmail.comhttps://orcid.org/0000-0002-8782-703XНемкаеваР. Р.NemkayevaR. R.

магистр физ.-техн. наук

г. Алматы

Master of Phys.-Tech Sciences

Almaty

quasisensus@mail.ruhttps://orcid.org/0000-0003-4804-5323ГусейновН. Г.GuseinovN. G.

магистр физ.-техн. наук

г. Алматы

Master of Phys.-Tech Sciences

Almaty

solar_neo@mail.ruhttps://orcid.org/0000-0002-0657-422XМархабаеваА. А.MarkhabayevaA. A.

PhD

г. Алматы

PhD

Almaty

aiko_marx@mail.ruhttps://orcid.org/0000-0003-1381-4532МухаметкаримовЕ. С.MukhametkarimovYe. S.

PhD, ассоц. профессор, доцент

г. Алматы

PhD, Associate Professor

Almaty

m.c.erzhan@mail.ruКазахский национальный университет им. аль-ФарабиКазахстанAl-Farabi Kazakh National University, Department of Physics and TechnologyKazakhstan202425122024214210218Copyright © Кошанова А.Б., Немкаева Р.Р., Гусейнов Н.Г., Мархабаева А.А., Мухаметкаримов Е.С., 20242024Кошанова А.Б., Немкаева Р.Р., Гусейнов Н.Г., Мархабаева А.А., Мухаметкаримов Е.С.Koshanova A.B., Nemkayeva R.R., Guseinov N.G., Markhabayeva A.A., Mukhametkarimov Y.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestnik.kbtu.edu.kz/jour/article/view/1552

Главным недостатком традиционных оксидов металлов, в том числе оксида цинка (ZnO), является слабое поглощение света в видимом диапазоне. Из множества путей решения данной проблемы создание их композиции с наночастицами (NPs) благородных металлов является наиболее интересным как с практической, так и с теоретической точки зрения. Благодаря эффекту локализованного поверхностного плазмонного резонанса (ЛППР), характеризующегося полосой поглощения света в видимом диапазоне, функциональность оксидных полупроводников может быть существенно улучшена. В этой работе представлены результаты получения композитных пленок на основе ZnO с наночастицами благородных металлов (серебра Ag, золота Au и их сплава AgAu) методом магнетронного распыления, а также анализ эффекта ЛППР в данных композитах. В пленках ZnO:AgNPs ЛППР поглощение наблюдалось на 475 нм, а для ZnO:AuNPs – на 535 нм. Сплавленные наночастицы AuAg демонстрируют максимум с пиком в промежуточном интервале двух этих значений, т.е. в области 508 нм. Полученные данные свидетельствуют о том, что, контролируя состав наночастиц благородных металлов, можно эффективно управлять полосой поглощения света в видимом диапазоне излучения.

The main disadvantage of traditional metal oxides, including zinc oxide (ZnO), is poor absorption of light in the visible range. Among the many ways to solve this problem, the creation of their composition with noble metal nanoparticles (NPs) is the most interesting from both practical and theoretical points of view. Due to the effect of localized surface plasmon resonance (LSPR), characterized by a light absorption band in the visible range, the functionality of oxide semiconductors can be significantly improved. This work presents the results of preparation of composite films based on ZnO with nanoparticles of noble metals (silver Ag, gold Au and their alloy AgAu) by magnetron sputtering, as well as the analysis of the LSPR effect in these composites. In ZnO:AgNPs films, the LSPR absorption was observed at 475 nm, while for ZnO:AuNPs at 535 nm. The AuAg alloy nanoparticles exhibit a maximum in the intermediate interval of these two values, i.e., in the region of 508 nm. The obtained data indicate that by controlling the composition of noble metal nanoparticles it is possible to effectively control the light absorption band in the visible range.

оксид цинкананочастицысереброзолотолокализованный поверхностный плазмонный резонансмагнетронное распылениеzinc oxidenanoparticlessilvergoldlocalized surface plasmon resonancemagnetron sputteringReferencesKhurana K., Jaggi N. Localized Surface Plasmonic Properties of Au and Ag Nanoparticles for Sensors: A Review. Plasmonics, 2021, no.16, pp. 981–999.Khurana K., Jaggi N. Localized Surface Plasmonic Properties of Au and Ag Nanoparticles for Sensors: A Review. Plasmonics, 2021, no.16, pp. 981–999.Guglielmelli A., Pierini F., Tabiryan N., Umeton C., Bunning T.J., De Sio L. Thermoplasmonics with Gold Nanoparticles: A New Weapon in Modern Optics and Biomedicine. Adv. Photonics Res. 2021, no. 2, p. 2000198.Guglielmelli A., Pierini F., Tabiryan N., Umeton C., Bunning T.J., De Sio L. Thermoplasmonics with Gold Nanoparticles: A New Weapon in Modern Optics and Biomedicine. Adv. Photonics Res. 2021, no. 2, p. 2000198.F.Y. Alzoubi, Ahmad A. Ahmad, Ihsan A. Aljarrah, A.B. Migdadi, and Qais M. Al-Bataineh. Localize surface plasmon resonance of silver nanoparticles using Mie theory. J. Mater Sci: Mater Electron, 2023, no. 34, p. 2128.F.Y. Alzoubi, Ahmad A. Ahmad, Ihsan A. Aljarrah, A.B. Migdadi, and Qais M. Al-Bataineh. Localize surface plasmon resonance of silver nanoparticles using Mie theory. J. Mater Sci: Mater Electron, 2023, no. 34, p. 2128.Koichi Okamoto, Daisuke Tanaka, Tetsuya Matsuyama, Kenji Wada, Yusuke Arima and Kaoru Tamada. Design and Optimization of Silver Nanostructured Arrays in Plasmonic Metamaterials for Sensitive Imaging Applications. J. Photonics, 2024, vol. 11, no. 4, p. 292.Koichi Okamoto, Daisuke Tanaka, Tetsuya Matsuyama, Kenji Wada, Yusuke Arima and Kaoru Tamada. Design and Optimization of Silver Nanostructured Arrays in Plasmonic Metamaterials for Sensitive Imaging Applications. J. Photonics, 2024, vol. 11, no. 4, p. 292.Novikov S.M., Popok V.N., Fiutowski J., Arsenin A.V. and Volkov V.S. Plasmonic properties of nanostructured graphene with silver nanoparticles. J. Phys.: Conf. Ser., 2020, no. 1461, p. 012119.Novikov S.M., Popok V.N., Fiutowski J., Arsenin A.V. and Volkov V.S. Plasmonic properties of nanostructured graphene with silver nanoparticles. J. Phys.: Conf. Ser., 2020, no. 1461, p. 012119.Baffou G., Cichos F., Quidant R. Applications and Challenges of Thermoplasmonics. Nat. Mater., 2020, no. 19, pp. 946–958.Baffou G., Cichos F., Quidant R. Applications and Challenges of Thermoplasmonics. Nat. Mater., 2020, no. 19, pp. 946–958.Chehadi Z., Girardon J.S., Capron M., Dumeignil F., Jradi S. Thermoplasmonic-Induced Energy-Efficient Catalytic Oxidation of Glycerol over Gold Supported Catalysts Using Visible Light at Ambient Temperature. Appl. Catal. A Gen., 2019, no. 572, pp. 9–14.Chehadi Z., Girardon J.S., Capron M., Dumeignil F., Jradi S. Thermoplasmonic-Induced Energy-Efficient Catalytic Oxidation of Glycerol over Gold Supported Catalysts Using Visible Light at Ambient Temperature. Appl. Catal. A Gen., 2019, no. 572, pp. 9–14.Brognara A., Bricchi B.R., William L., Brinza O., Konstantakopoulou M., Bassi A.L., Ghidelli M., Lidgi-Guigui N. New Mechanism for Long Photo-Induced Enhanced Raman Spectroscopy in Au Nanoparticles Embedded in TiO2. Small, 2022, no. 18, p. 2201088.Brognara A., Bricchi B.R., William L., Brinza O., Konstantakopoulou M., Bassi A.L., Ghidelli M., Lidgi-Guigui N. New Mechanism for Long Photo-Induced Enhanced Raman Spectroscopy in Au Nanoparticles Embedded in TiO2. Small, 2022, no. 18, p. 2201088.Ye J., Arul R., Nieuwoudt M.K., Dong J., Zhang T., Dai L., Greenham N.C., Rao A., Hoye R.L.Z., Gao W. et al. Under-standing the Chemical Mechanism behind Photoinduced Enhanced Raman Spectroscopy. J. Phys. Chem. Lett., 2023, no. 14, pp. 4607–4616.Ye J., Arul R., Nieuwoudt M.K., Dong J., Zhang T., Dai L., Greenham N.C., Rao A., Hoye R.L.Z., Gao W. et al. Under-standing the Chemical Mechanism behind Photoinduced Enhanced Raman Spectroscopy. J. Phys. Chem. Lett., 2023, no. 14, pp. 4607–4616.Lyu P., Espinoza R., Nguyen S.C. Photocatalysis of Metallic Nanoparticles: Interband vs Intraband Induced Mechanisms. J. Phys. Chem. C, 2023, vol. 127, no. 32, pp. 15685–15698.Lyu P., Espinoza R., Nguyen S.C. Photocatalysis of Metallic Nanoparticles: Interband vs Intraband Induced Mechanisms. J. Phys. Chem. C, 2023, vol. 127, no. 32, pp. 15685–15698.Rituraj Borah, Rajeshreddy Ninakanti, Sara Bals & Sammy W. Verbruggen. Plasmon resonance of gold and silver nanoparticle arrays in the Kretschmann (attenuated total reflectance) vs. direct incidence configuration. J. Scientific Reports, 2022, vol. 12, Article number: 15738.Rituraj Borah, Rajeshreddy Ninakanti, Sara Bals & Sammy W. Verbruggen. Plasmon resonance of gold and silver nanoparticle arrays in the Kretschmann (attenuated total reflectance) vs. direct incidence configuration. J. Scientific Reports, 2022, vol. 12, Article number: 15738.Alexis Loiseau, Victoire Asila, Gabriel Boitel-Aullen, Mylan Lam, Michèle Salmain and Souhir Boujday. Silver-Based Plasmonic Nanoparticles for and Their Use in Biosensing. J. Biosensors (Basel), 2019 Jun., vol. 9, no. 2, p. 78.Alexis Loiseau, Victoire Asila, Gabriel Boitel-Aullen, Mylan Lam, Michèle Salmain and Souhir Boujday. Silver-Based Plasmonic Nanoparticles for and Their Use in Biosensing. J. Biosensors (Basel), 2019 Jun., vol. 9, no. 2, p. 78.Karunakaran C., Rajeswari V., Gomathisankar P. Combustion synthesis of ZnO and Ag-doped ZnO and their bactericidal and photocatalytic activities. J. Superlattices and Microstructures, 2011, vol. 50, Issue 3, pp. 234–241.Karunakaran C., Rajeswari V., Gomathisankar P. Combustion synthesis of ZnO and Ag-doped ZnO and their bactericidal and photocatalytic activities. J. Superlattices and Microstructures, 2011, vol. 50, Issue 3, pp. 234–241.Linhua Xu, Gaige Zheng, Lilong Zhao, Shixin Pei. Two different mechanisms on UV emission enhancement in Ag-doped ZnO thin films. J. Journal of Luminescence, 2015, vol. 158, pp. 396–400.Linhua Xu, Gaige Zheng, Lilong Zhao, Shixin Pei. Two different mechanisms on UV emission enhancement in Ag-doped ZnO thin films. J. Journal of Luminescence, 2015, vol. 158, pp. 396–400.Zhuang T.-T., Liu Y., Li Y., Sun M., Sun Z.-J., Du P.-W., Jiang J., Yu S.-H. 1D Colloidal Hetero-Nanomaterials with Programmed Semiconductor Morphology and Metal Location for Enhancing Solar Energy Conversion. J. Small., 2017, no. 13, p. 1602629.Zhuang T.-T., Liu Y., Li Y., Sun M., Sun Z.-J., Du P.-W., Jiang J., Yu S.-H. 1D Colloidal Hetero-Nanomaterials with Programmed Semiconductor Morphology and Metal Location for Enhancing Solar Energy Conversion. J. Small., 2017, no. 13, p. 1602629.Mwankemwa B.S., Nambala F.J., Kyeyune F., Hlatshwayo T.T., Nel J.M., Diale M. Materials Science in Semiconductor Processing, 2017, no. 71, pp. 209–216.Mwankemwa B.S., Nambala F.J., Kyeyune F., Hlatshwayo T.T., Nel J.M., Diale M. Materials Science in Semiconductor Processing, 2017, no. 71, pp. 209–216.Prikhodko O., Dosseke U., Nemkayeva R., Rofman O., Guseinov N., Mukhametkarimov Ye. Localized surface plasmon resonance phenomenon in Ag/Au-WO3-x nanocomposite thin films. J. Thin Solid Films, 2022, no. 757, p. 139387.Prikhodko O., Dosseke U., Nemkayeva R., Rofman O., Guseinov N., Mukhametkarimov Ye. Localized surface plasmon resonance phenomenon in Ag/Au-WO3-x nanocomposite thin films. J. Thin Solid Films, 2022, no. 757, p. 139387.Asaad A. Kamil, Nabeel A. Bakr, Mubarak T.H., Al-Zanganawee J. Effect of Au and Ag nanoparticles addition on the morphological, structural and optical properties of ZnO thin films deposited by sol-gel method. J. Journal of Ovonic Research, 2022, vol. 18, no. 3, pp. 431–442.Asaad A. Kamil, Nabeel A. Bakr, Mubarak T.H., Al-Zanganawee J. Effect of Au and Ag nanoparticles addition on the morphological, structural and optical properties of ZnO thin films deposited by sol-gel method. J. Journal of Ovonic Research, 2022, vol. 18, no. 3, pp. 431–442.Ziaul Raza Khan, Mohd Shoeb Khan, Mohammad Zulfequar, Mohd Shahid Khan. Optical and Structural Properties of ZnO Thin Films Fabricated by Sol-Gel Method. J. Materials Sciences and Applications, 2011, no. 2, pp. 340–345.Ziaul Raza Khan, Mohd Shoeb Khan, Mohammad Zulfequar, Mohd Shahid Khan. Optical and Structural Properties of ZnO Thin Films Fabricated by Sol-Gel Method. J. Materials Sciences and Applications, 2011, no. 2, pp. 340–345.Kumar P., Som S., Pandey M. K, Das S, Chanda A, Singh J. Journal of Alloys and Compounds 744, 2018, pp. 64–74.Kumar P., Som S., Pandey M. K, Das S, Chanda A, Singh J. Journal of Alloys and Compounds 744, 2018, pp. 64–74.Prabhu S., Pudukudy M., Sohila S., Harish S., Navaneethan M., Navaneethan D., Ramesh R., Hayakawa Y., Optical Materials, 2018, no. 79, pp. 186–195.Prabhu S., Pudukudy M., Sohila S., Harish S., Navaneethan M., Navaneethan D., Ramesh R., Hayakawa Y., Optical Materials, 2018, no. 79, pp. 186–195.Changhwan Lee, Yujin Park and Jeong Young Park. Hot electrons generated by intraband and interband transition detected using a plasmonic Cu/TiO2 nanodiode. RSC Adv., 2019, no. 9, pp. 18371–18376.Changhwan Lee, Yujin Park and Jeong Young Park. Hot electrons generated by intraband and interband transition detected using a plasmonic Cu/TiO2 nanodiode. RSC Adv., 2019, no. 9, pp. 18371–18376.Siti Huzaimah Ributa, Che Azurahanim Che Abdullaha, Mohd Zaki Mohammad Yusof. Investigations of structural and optical properties of zinc oxide thin films growth on various substrates. J. Results in Physics, 2019, vol. 13, p. 102146.Siti Huzaimah Ributa, Che Azurahanim Che Abdullaha, Mohd Zaki Mohammad Yusof. Investigations of structural and optical properties of zinc oxide thin films growth on various substrates. J. Results in Physics, 2019, vol. 13, p. 102146.Quinten M. Optical Properties of Nanoparticle Systems: Mie and Beyond, November 2010, p. 502. ISBN: 978-3-527-63315-9.Quinten M. Optical Properties of Nanoparticle Systems: Mie and Beyond, November 2010, p. 502. ISBN: 978-3-527-63315-9.Shaheen Husain, Aditya Nandi, Faizan Zarreen Simnani, Utsa Saha, Aishee Ghosh, Adrija Sinha, Aarya Sahay, Shailesh Kumar Samal, Pritam Kumar Panda and Suresh K. Verma. Emerging Trends in Advanced Translational Applications of Silver Nanoparticles: A Progressing Dawn of Nanotechnology. J. Funct. Biomater., 2023, 14, 47.Shaheen Husain, Aditya Nandi, Faizan Zarreen Simnani, Utsa Saha, Aishee Ghosh, Adrija Sinha, Aarya Sahay, Shailesh Kumar Samal, Pritam Kumar Panda and Suresh K. Verma. Emerging Trends in Advanced Translational Applications of Silver Nanoparticles: A Progressing Dawn of Nanotechnology. J. Funct. Biomater., 2023, 14, 47.Takeo Tomiyama, Ikuo Mukai, Hiroshi Yamazaki and Yoshihiko Takeda. Optical properties of silver nanowire/polymer composite films: absorption, scattering and color difference. J. Optical Materials Express, 2020, vol. 10, Issue 12, pp. 3202–3214.Takeo Tomiyama, Ikuo Mukai, Hiroshi Yamazaki and Yoshihiko Takeda. Optical properties of silver nanowire/polymer composite films: absorption, scattering and color difference. J. Optical Materials Express, 2020, vol. 10, Issue 12, pp. 3202–3214.

The authors declare that there are no conflicts of interest present.