kaz29Вестник Казахстанско-Британского технического университетаHerald of the Kazakh-British Technical University1998-66882959-8109Казахстанско-Британский Технический Университет10.55452/1998-6688-2024-21-4-186-195kaz29-1550Research ArticleФИЗИЧЕСКИЕ НАУКИPHYSICAL SCIENCESИЗГОТОВЛЕНИЕ ЭЛЕКТРОДОВ СУПЕРКОНДЕНСАТОРОВ С ВЫСОКОЙ ПРОИЗВОДИТЕЛЬНОСТЬЮ НА ОСНОВЕ ГРАФЕНОПОДОБНОГО УГЛЕРОДА, ПОЛУЧЕННОГО ИЗ ОТХОДОВ ЧАЯPRODUCTION OF HIGH-PERFORMANCE SUPERCAPACITOR ELECTRODES BASED ON GRAPHENE-LIKE CARBON OBTAINED FROM TEA WASTEhttps://orcid.org/0009-0007-5211-6098ДүйсенбекӘ. Н.DuisenbekA. N.

PhD докторант

г. Алматы

PhD student

Almaty

aselka_star@mail.ruhttps://orcid.org/0000-0002-0392-6015БейсеноваЕ. Е.BeissenovaE. E.

PhD

г. Алматы

PhD

Almaty

mamyrbayeva.e@gmail.comhttps://orcid.org/0000-0001-6880-7693БейсеновР. Е.BeissenovR. E.

PhD

г. Алматы

PhD

Almaty

renat7787@mail.ruhttps://orcid.org/0000-0002-8998-0409АсқарұлыҚ.AskarulyK.

PhD

г. Алматы

PhD

Almaty

k.askaruly@gmail.comhttps://orcid.org/0000-0001-7733-0903ПриходькоН. Г.PrikhodkoN. G.

PhD, д.х.н., профессор

г. Алматы

PhD, Doctor of Chemical Sciences, Professor

Almaty

nik99951@mail.ruТуганбаевА. Б.TuganbaevА. B.

главный инженер

г. Талдыкорган

main engineer

Taldykorgan

tatek.oid@mail.ruКазНИТУ им. К.И. Сатпаева; Институт проблем горенияКазахстанSatbayev University; Institute of Combustion ProblemsKazakhstanИнститут проблем горения; Казахстанско-Британский технический университетКазахстанInstitute of Combustion Problems; Kazakh-British Technical UniversityKazakhstanКазНИТУ им. К.И. Сатпаева; Казахстанско-Британский технический университет; Алматинский университет энергетики и связи им. Г. ДаукееваКазахстанSatbayev University; Kazakh-British Technical University; G. Daukeev Almaty University of Energy and CommunicationsKazakhstanИнститут проблем горения; Алматинский университет энергетики и связи им. Г. ДаукееваКазахстанInstitute of Combustion Problems; G. Daukeev Almaty University of Energy and CommunicationsKazakhstanТалдыкорганская акционерная транспортно-электросетевая компанияКазахстан«Taldykorgan Joint-Stock Transport Electric Network Company»Kazakhstan202424122024214186195Copyright © Дүйсенбек Ә.Н., Бейсенова Е.Е., Бейсенов Р.Е., Асқарұлы Қ., Приходько Н.Г., Туганбаев А.Б., 20242024Дүйсенбек Ә.Н., Бейсенова Е.Е., Бейсенов Р.Е., Асқарұлы Қ., Приходько Н.Г., Туганбаев А.Б.Duisenbek A.N., Beissenova E.E., Beissenov R.E., Askaruly K., Prikhodko N.G., Tuganbaev А.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestnik.kbtu.edu.kz/jour/article/view/1550

В данной статье представлены результаты исследования по изготовлению активного материала для электродов суперконденсатора из графеноподобного углерода, полученного из чайных отходов карбонизацией при температуре 550°С с последующей термохимической активацией с гидроксидом калия в соотношении 1:4 при температуре 850 °С в кварцевой трубчатой печи. Структура и морфология полученного пористого графеноподобного углерода на основе чайных отходов исследована на сканирующем электронном микроскопе (СЭМ), метода Брунауэра-Эммета-Теллера (БЭТ), рентгеновской дифракции и рамановской спектроскопии. Площадь поверхности активированного пористого графеноподобного углерода из чайных отходов составила 2407 м2/г. Электрохимические и вольтамперные характеристики собранного двухслойного суперконденсатора с электродом из ГПУ-ЧО были определены с использованием потенциостат-гальваностата и исследованы на электрохимической рабочей станции Elins P-40X. Полученные результаты показали высокую удельную емкость в 182 Ф/г и кулоновскую эффективность в 96% при плотности тока 2А/г, также материал продемонстрировал низкое сопротивление переноса заряда, составляющее около 1,5 Ом, что подчеркивает эффективность использования графеноподобного углерода, полученного из отходов чая, демонстрируя его потенциал в качестве многообещающего материала для суперконденсаторов.

This article presents the results of a study on the production of active material for supercapacitor electrodes from graphene-like carbon obtained from tea waste, carbonization at a temperature of 550°C, followed by thermochemical activation using potassium hydroxide in a ratio of 1:4 at a temperature of 850°C in a quartz tube furnace. The structure and morphology of the resulting porous graphene-like carbon based on tea waste were investigated using scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET), X-ray diffraction, and Raman spectroscopy. The surface area of activated porous graphene-like carbon from tea waste was 2407 m2/g. Electrochemical characterization of the assembled supercapacitor using GLC-TW was performed on an Elins P-40X electrochemical workstation and showed high specific capacitance values of 182 F/g, as well as a Coulombic efficiency of 96% at a current density of 1 A/g and the material also demonstrated a low charge transfer resistance of about 1.5 Ohms. These results highlight the effectiveness of using graphene-like carbon derived from tea waste, demonstrating its potential as a promising material for supercapacitors.

суперконденсаторэлектродграфеноподобный углеродактивированный уголькарбонизациятермохимическая активацияsupercapacitorelectrodegraphene-like carbonactivated carboncarbonizationthermochemical activationРабота выполнена в рамках программы «Грантовое финансирование научных исследований» АР15473245 Министерства науки и высшего образования Республики Казахстан.ReferencesFrackowiak E., Abbas Q., Béguin F. Carbon/carbon supercapacitors, Journal of Energy Chemistry, 2013, vol. 22, pp. 226–240. https://doi.org/10.1016/S2095-4956(13)60028-5.Frackowiak E., Abbas Q., Béguin F. Carbon/carbon supercapacitors, Journal of Energy Chemistry, 2013, vol. 22, pp. 226–240. https://doi.org/10.1016/S2095-4956(13)60028-5.Gao Y., Zhou Y.S., Qian M., He X.N., Redepenning J., Goodman P., Li H.M., Jiang L., Lu Y.F. Chemical activation of carbon nano-onions for high-rate supercapacitor electrodes, Carbon, 2013, vol. 51, pp. 52–58. https://doi.org/10.1016/j.carbon.2012.08.009.Gao Y., Zhou Y.S., Qian M., He X.N., Redepenning J., Goodman P., Li H.M., Jiang L., Lu Y.F. Chemical activation of carbon nano-onions for high-rate supercapacitor electrodes, Carbon, 2013, vol. 51, pp. 52–58. https://doi.org/10.1016/j.carbon.2012.08.009.Fu M., Huang J., Feng S., Zhang T., Qian P.-C., Wong W.-Y. One-step solid-state pyrolysis of bio-wastes to synthesize multi-hierarchical porous carbon for ultra-long life supercapacitors, Mater. Chem. Front., 2021, vol. 5, pp. 2320–2327. https://doi.org/10.1039/D0QM00960A.Fu M., Huang J., Feng S., Zhang T., Qian P.-C., Wong W.-Y. One-step solid-state pyrolysis of bio-wastes to synthesize multi-hierarchical porous carbon for ultra-long life supercapacitors, Mater. Chem. Front., 2021, vol. 5, pp. 2320–2327. https://doi.org/10.1039/D0QM00960A.Tian Q., Wang X., Xu X., Zhang M., Wang L., Zhao X., An Z., Yao H., Gao J. A novel porous carbon material made from wild rice stem and its application in supercapacitors, Materials Chemistry and Physics, 2018, vol. 213, pp. 267–276. https://doi.org/10.1016/j.matchemphys.2018.04.026.Tian Q., Wang X., Xu X., Zhang M., Wang L., Zhao X., An Z., Yao H., Gao J. A novel porous carbon material made from wild rice stem and its application in supercapacitors, Materials Chemistry and Physics, 2018, vol. 213, pp. 267–276. https://doi.org/10.1016/j.matchemphys.2018.04.026.Laheäär A., Przygocki P., Abbas Q., Béguin F. Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors, Electrochemistry Communications, 2015, vol. 60, pp. 21–25. https://doi.org/10.1016/j.elecom.2015.07.022.Laheäär A., Przygocki P., Abbas Q., Béguin F. Appropriate methods for evaluating the efficiency and capacitive behavior of different types of supercapacitors, Electrochemistry Communications, 2015, vol. 60, pp. 21–25. https://doi.org/10.1016/j.elecom.2015.07.022.Abbas A., Tabish T.A., Bull S.J., Lim T.M., Phan A.N. High yield synthesis of graphene quantum dots from biomass waste as a highly selective probe for Fe3+ sensing, Sci Rep., 2020, vol. 10, 21262. https://doi.org/10.1038/s41598-020-78070-2.Abbas A., Tabish T.A., Bull S.J., Lim T.M., Phan A.N. High yield synthesis of graphene quantum dots from biomass waste as a highly selective probe for Fe3+ sensing, Sci Rep., 2020, vol. 10, 21262. https://doi.org/10.1038/s41598-020-78070-2.Wang Y., Shi Z., Huang Y., Ma Y., Wang C., Chen M., Chen Y. Supercapacitor Devices Based on Graphene Materials, J. Phys. Chem., 2009, vol. 113, pp. 13103–13107. https://doi.org/10.1021/jp902214f.Wang Y., Shi Z., Huang Y., Ma Y., Wang C., Chen M., Chen Y. Supercapacitor Devices Based on Graphene Materials, J. Phys. Chem., 2009, vol. 113, pp. 13103–13107. https://doi.org/10.1021/jp902214f.Yeleuov M., Daulbayev C., Taurbekov A., Abdisattar A., Ebrahim R., Kumekov S., Prikhodko N., Lesbayev B., Batyrzhan K. Synthesis of graphene-like porous carbon from biomass for electrochemical energy storage applications, Diamond and Related Materials, 2021, vol. 119, 108560. https://doi.org/10.1016/j.diamond.2021.108560.Yeleuov M., Daulbayev C., Taurbekov A., Abdisattar A., Ebrahim R., Kumekov S., Prikhodko N., Lesbayev B., Batyrzhan K. Synthesis of graphene-like porous carbon from biomass for electrochemical energy storage applications, Diamond and Related Materials, 2021, vol. 119, 108560. https://doi.org/10.1016/j.diamond.2021.108560.Roy A., Kar S., Ghosal R., Naskar K., Bhowmick A.K. Facile Synthesis and Characterization of Few-Layer Multifunctional Graphene from Sustainable Precursors by Controlled Pyrolysis, Understanding of the Graphitization Pathway, and Its Potential Application in Polymer Nanocomposites, ACS Omega, 2021, vol. 6, pp. 1809–1822. https://doi.org/10.1021/acsomega.0c03550.Roy A., Kar S., Ghosal R., Naskar K., Bhowmick A.K. Facile Synthesis and Characterization of Few-Layer Multifunctional Graphene from Sustainable Precursors by Controlled Pyrolysis, Understanding of the Graphitization Pathway, and Its Potential Application in Polymer Nanocomposites, ACS Omega, 2021, vol. 6, pp. 1809–1822. https://doi.org/10.1021/acsomega.0c03550.Prikhod’ko N.G., Mansurov Z.A., Auelkhankyzy M., Lesbaev B.T., Nazhipkyzy M., Smagulova G.T. Flame synthesis of graphene layers at low pressure, Russ. J. Phys. Chem., 2015, vol. 9, pp. 743–747. https://doi.org/10.1134/S1990793115050115.Prikhod’ko N.G., Mansurov Z.A., Auelkhankyzy M., Lesbaev B.T., Nazhipkyzy M., Smagulova G.T. Flame synthesis of graphene layers at low pressure, Russ. J. Phys. Chem., 2015, vol. 9, pp. 743–747. https://doi.org/10.1134/S1990793115050115.Song X., Ma X., Li Y., Ding L., Jiang R. Tea waste derived microporous active carbon with enhanced double-layer supercapacitor behaviors, Applied Surface Science, 2019, vol. 487, pp. 189–197. https://doi.org/10.1016/j.apsusc.2019.04.277.Song X., Ma X., Li Y., Ding L., Jiang R. Tea waste derived microporous active carbon with enhanced double-layer supercapacitor behaviors, Applied Surface Science, 2019, vol. 487, pp. 189–197. https://doi.org/10.1016/j.apsusc.2019.04.277.Bhoyate S., Ranaweera C.K., Zhang C., Morey T., Hyatt M., Kahol P.K., Ghimire M., Mishra S.R., Gupta R.K. Eco-Friendly and High Performance Supercapacitors for Elevated Temperature Applications Using Recycled Tea Leaves, Global Challenges, 2017, vol. 1, 1700063. https://doi.org/10.1002/gch2.201700063.Bhoyate S., Ranaweera C.K., Zhang C., Morey T., Hyatt M., Kahol P.K., Ghimire M., Mishra S.R., Gupta R.K. Eco-Friendly and High Performance Supercapacitors for Elevated Temperature Applications Using Recycled Tea Leaves, Global Challenges, 2017, vol. 1, 1700063. https://doi.org/10.1002/gch2.201700063.Adan-Mas A., Alcaraz L., Arévalo-Cid P., López-Gómez Félix. A., Montemor F. Coffee-derived activated carbon from second biowaste for supercapacitor applications, Waste Management, 2021, vol. 120, pp. 280–289. https://doi.org/10.1016/j.wasman.2020.11.043.Adan-Mas A., Alcaraz L., Arévalo-Cid P., López-Gómez Félix. A., Montemor F. Coffee-derived activated carbon from second biowaste for supercapacitor applications, Waste Management, 2021, vol. 120, pp. 280–289. https://doi.org/10.1016/j.wasman.2020.11.043.Li Y., Li Z., Xing B., Li H., Ma Z., Zhang W., Reubroycharoen P., Wang S. Green conversion of bamboo chips into high-performance phenol adsorbent and supercapacitor electrodes by simultaneous activation and nitrogen doping, Journal of Analytical and Applied Pyrolysis, 2021, vol. 155, 105072. https://doi.org/10.1016/j.jaap.2021.105072.Li Y., Li Z., Xing B., Li H., Ma Z., Zhang W., Reubroycharoen P., Wang S. Green conversion of bamboo chips into high-performance phenol adsorbent and supercapacitor electrodes by simultaneous activation and nitrogen doping, Journal of Analytical and Applied Pyrolysis, 2021, vol. 155, 105072. https://doi.org/10.1016/j.jaap.2021.105072.Ferrari A.C. Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects, Solid State Communications, 2007, vol. 143, pp. 47–57. https://doi.org/10.1016/j.ssc.2007.03.052.Ferrari A.C. Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects, Solid State Communications, 2007, vol. 143, pp. 47–57. https://doi.org/10.1016/j.ssc.2007.03.052.Bleu Y., Bourquard F., Loir A., Barnier V., Garrelie F., Donnet C. Raman study of the substrate influence on graphene synthesis using a solid carbon source via rapid thermal annealing, J Raman Spectrosc, 2019, vol. 50, pp. 1630–1641. https://doi.org/10.1002/jrs.5683.Bleu Y., Bourquard F., Loir A., Barnier V., Garrelie F., Donnet C. Raman study of the substrate influence on graphene synthesis using a solid carbon source via rapid thermal annealing, J Raman Spectrosc, 2019, vol. 50, pp. 1630–1641. https://doi.org/10.1002/jrs.5683.He X., Ling P., Yu M., Wang X., Zhang X., Zheng M. Rice husk-derived porous carbons with high capacitance by ZnCl2 activation for supercapacitors, Electrochimica Acta, 2013, vol. 105, pp. 635–641. https://doi.org/10.1016/j.electacta.2013.05.050.He X., Ling P., Yu M., Wang X., Zhang X., Zheng M. Rice husk-derived porous carbons with high capacitance by ZnCl2 activation for supercapacitors, Electrochimica Acta, 2013, vol. 105, pp. 635–641. https://doi.org/10.1016/j.electacta.2013.05.050.Han J., Xu G., Ding B., Pan J., Dou H., MacFarlane D.R. Porous nitrogen-doped hollow carbon spheres derived from polyaniline for high performance supercapacitors, J. Mater. Chem. A, 2014, vol. 2, pp. 5352–5357. https://doi.org/10.1039/C3TA15271E.Han J., Xu G., Ding B., Pan J., Dou H., MacFarlane D.R. Porous nitrogen-doped hollow carbon spheres derived from polyaniline for high performance supercapacitors, J. Mater. Chem. A, 2014, vol. 2, pp. 5352–5357. https://doi.org/10.1039/C3TA15271E.Kang W., Lin B., Huang G., Zhang C., Yao Y., Hou W., Xu B., Xing B. Peanut bran derived hierarchical porous carbon for supercapacitor, J Mater Sci: Mater Electron, 2018, vol. 29, pp. 6361–6368. https://doi.org/10.1007/s10854-018-8615-1.Kang W., Lin B., Huang G., Zhang C., Yao Y., Hou W., Xu B., Xing B. Peanut bran derived hierarchical porous carbon for supercapacitor, J Mater Sci: Mater Electron, 2018, vol. 29, pp. 6361–6368. https://doi.org/10.1007/s10854-018-8615-1.Hao X., Wang J., Ding B., Wang Y., Chang Z., Dou H., Zhang X. Bacterial-cellulose-derived interconnected meso-microporous carbon nanofiber networks as binder-free electrodes for high-performance supercapacitors, Journal of Power Sources, 2017, vol. 352, pp. 34–41. https://doi.org/10.1016/j.jpowsour.2017.03.088.Hao X., Wang J., Ding B., Wang Y., Chang Z., Dou H., Zhang X. Bacterial-cellulose-derived interconnected meso-microporous carbon nanofiber networks as binder-free electrodes for high-performance supercapacitors, Journal of Power Sources, 2017, vol. 352, pp. 34–41. https://doi.org/10.1016/j.jpowsour.2017.03.088.Sun J., Niu J., Liu M., Ji J., Dou M., Wang F. Biomass-derived nitrogen-doped porous carbons with tailored hierarchical porosity and high specific surface area for high energy and power density supercapacitors, Applied Surface Science, 2018, vol. 427, pp. 807–813. https://doi.org/10.1016/j.apsusc.2017.07.220.Sun J., Niu J., Liu M., Ji J., Dou M., Wang F. Biomass-derived nitrogen-doped porous carbons with tailored hierarchical porosity and high specific surface area for high energy and power density supercapacitors, Applied Surface Science, 2018, vol. 427, pp. 807–813. https://doi.org/10.1016/j.apsusc.2017.07.220.Peng C., Yan X., Wang R., Lang J., Ou Y., Xue Q. Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes, Electrochimica Acta, 2013, vol. 87, pp. 401–408. https://doi.org/10.1016/j.electacta.2012.09.082.Peng C., Yan X., Wang R., Lang J., Ou Y., Xue Q. Promising activated carbons derived from waste tea-leaves and their application in high performance supercapacitors electrodes, Electrochimica Acta, 2013, vol. 87, pp. 401–408. https://doi.org/10.1016/j.electacta.2012.09.082.Ratnaji T., L. John Kennedy. Hierarchical porous carbon derived from tea waste for energy storage applications: Waste to worth, Diamond & Related Materials, 2020. https://doi.org/10.1016/j.diamond.2020.108100.Ratnaji T., L. John Kennedy. Hierarchical porous carbon derived from tea waste for energy storage applications: Waste to worth, Diamond & Related Materials, 2020. https://doi.org/10.1016/j.diamond.2020.108100.

The authors declare that there are no conflicts of interest present.