kaz29Вестник Казахстанско-Британского технического университетаHerald of the Kazakh-British Technical University1998-66882959-8109Казахстанско-Британский Технический Университет10.55452/1998-6688-2024-21-1-114-122kaz29-1028Research ArticleФИЗИЧЕСКИЕ НАУКИPHYSICAL SCIENCESСИНТЕЗ МНОГОКОМПОНЕНТНЫХ КЕРАМИК ZRO2:WO3:AL2O3:MGOSYNTHESIS OF MULTICOMPONENT ZRO2:WO3:AL2O3:MGOhttps://orcid.org/0000-0002-0759-4329ГаранинЮ. А.GaraninYu. A.

докторант

010000, г. Астана

Doctoral student

010000, Astana

jorge.r2448@gmail.comhttps://orcid.org/0000-0001-9908-3034ШакирзяновР. И.ShakirzyanovR. I.

PhD

010000, г. Астана

PhD

010000, Astana

   

halfraf@mail.ruhttps://orcid.org/0000-0001-8832-7443КозловскийА. Л.KozlovskiyA. L. 

PhD

010000, г. Астана

PhD

010000, Astana

kozlovskiy.a@inp.kzhttps://orcid.org/0000-0003-2454-7177ШлимасД. И.ShlimasD. I.

PhD

010000, г. Астана

PhD

010000, Astana

shlimas@mail.ruhttps://orcid.org/0000-0002-9727-0511БоргековД. Б.BorgekovD. B.

PhD

010000, г. Астана

PhD

010000, Astana

borgekov@mail.comЕвразийский национальный университет им. Л.Н. Гумилева; Астанинский филиал Института ядерной физикиКазахстанL.N. Gumilyov Eurasian National University; Astana Branch of the Institute of Nuclear PhysicsKazakhstanЕвразийский национальный университет им. Л.Н. ГумилеваКазахстанL.N. Gumilyov Eurasian National UniversityKazakhstan202426032024211114122Copyright © Гаранин Ю.А., Шакирзянов Р.И., Козловский А.Л., Шлимас Д.И., Боргеков Д.Б., 20242024Гаранин Ю.А., Шакирзянов Р.И., Козловский А.Л., Шлимас Д.И., Боргеков Д.Б.Garanin Y.A., Shakirzyanov R.I., Kozlovskiy A.L., Shlimas D.I., Borgekov D.B.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://vestnik.kbtu.edu.kz/jour/article/view/1028

В данной работе был исследован фазовый состав и микроструктура многокомпонентных керамик ZrO2:WO3:Al2O3:MgO в зависимости от концентрации компонентов. Определены зависимости между концентрацией элементов в исходной шихте и фазовым составом, объемной усадкой, плотностью и микроструктурой синтезированных образцов. Методом рамановской спектроскопии установлено, что добавление к исходной матрице ZrO2:WO3 смеси Al2O3:MgO не приводит к образованию твердого раствора ZrO2:WO3:Al2O3:MgO. С увеличением содержания Al2O3:MgO происходит увеличение объемной усадки и плотности, что может быть связано с образованием жидкой фазы системы WO3:Al2O3 при температуре 1450 °С и, как следствие, более эффективной миграции пор и дефектов к поверхности. Анализ СЭМизображений поперечных сечений полученных образцов показал, что все образцы обладают развитой морфологией с различными формами зерен.

In this work, the phase composition and microstructure of multicomponent ZrO2:WO3:Al2O3:MgO ceramics were studied depending on the concentration of the components. The dependences between the concentration of elements in the initial charge and the phase composition, volume shrinkage, density and microstructure of synthesized samples are determined. It was found by Raman spectroscopy that the addition of an Al2O3:MgO mixture to the initial ZrO2:WO3 matrix does not lead to the formation of a ZrO2:WO3:Al2O3:MgO solid solution. With an increase in the content of Al2O3:MgO, there is an increase in volumetric shrinkage and density, which may be associated with the formation of the liquid phase of the WO3:Al2O3 system at a temperature of 1450 °C and, as a result, more efficient migration of pores and defects to the surface. The analysis of the SEM images of the cross sections of the obtained samples showed that all samples have a developed morphology with different grain shapes.

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The authors declare that there are no conflicts of interest present.